FREE ESSAY ON ORGANIC CHEMISTRY

ORGANIC CHEMISTRY

Organic compounds are covalently bonded compounds containing carbon, excluding carbonates
and oxides. Carbon atoms are unique because of their ability to bond by catenation, which
is forming long chains and rings from the covalent binding of an element to itself.
Besides bonding with itself, carbon atoms are able to bind to elements with similar
electronegativities. Organic compounds consist of carbon and these other elements. 
Hydrocarbons are the simplest organic compounds, composed of only carbon and hydrogen.
Saturated hydrocarbons are hydrocarbons in which each carbon atom in the molecule forms
four single covalent bonds with other atoms. Hydrocarbons that contain only single bonds
are alkanes.
The boiling point for alkanes increases with increasing molecular mass. The
carbon-hydrogen bonds of alkanes are nonpolar and the only forces of attraction between
nonpolar molecules are weak intermolecular forces. Methane, ethane, propane, and butane
are all gases at room temperature. Pentane, octane, and decane are all liquids at room
temperature. Heptadecane and eicosane are solids are room temperature.
Cycloalkanes are alkanes in which the carbon atoms are arranged in a ring, or cyclic,
structure.
In fractional distillation, components of a mixture are separated on the basis of boiling
point, by condensation of vapor in a fractionating column. The octane rating of a fuel is
a measure of its burning efficiency and its antiknock properties. The octane rating scale
is based on mixtures of 2,2,4-trimethylpentane, isooctane. Pure 2,2,4-trimethypentane is
very resistant to knocking and is assigned an octane number of 100. Pure heptane has an
octane number of 0 and burns with a lot of knocking. Increasing the percentage of
branched-chain alkanes in gasoline is one way to increase octane rating.
Unsaturated hydrocarbons are hydrocarbons in which not all carbon atoms have four single
covalent bonds. Alkenes are hydrocarbons that contain double covalent bonds.
Alkenes are nonpolar and show trends in properties similar to those of alkanes in boiling
points and physical states. -farnesene has 15 carbon atoms and 4 double bonds. It is
solid at room temperature and atmospheric pressure. It is found in the natural wax
covering of apples. Ethene is the hydrocarbon commercially produced in the greatest
quantity in the United States. It is used in the synthesis of many plastics and
commercially important alcohols. Ethene is also an important plant hormone.
Hydrocarbons with triple covalent bonds are alkynes. This triple bond requires that the
simplest alkyne has two carbon atoms.
Alkynes, as with other hydrocarbons, exhibit the same trends in boiling points and
physical state and are nonpolar. The smallest alkyne, ethyne, is a gas. The combustion of
ethyne when it is mixed with pure oxygen produces the intense heat of welding torches.
The common name of ethyne is acetylene, and these welding torches are commonly called
oxyacetylene torches.
Aromatic hydrocarbons are hydrocarbons with six-membered carbon rings and delocalized
electrons. Benzene is the primary aromatic hydrocarbon.
Benzene rings are chemically very stable, a property that can be explained by the concept
of delocalized electrons. Therefore, aromatic hydrocarbons are less reactive than alkenes
and alkynes are. Benzene, in the past, was used as a nonpolar solvent because of this
stability. However, benzene is both a poison and a carcinogen. It is nonpolar and has
limited solubility in water. Another aromatic hydrocarbon, 3,4-benzpyrene, is found in
coal tar, tar from cigarette smoke, and soot in heavily polluted urban areas. Shown from
studies, this compound is capable of causing cancer.
Alcohols are organic compounds that contain one or more hydroxyl groups. The general
formula for a class of organic compounds consists of the functional group and the letter
R, which stands for the rest of the molecule. The general formula for alcohols is R-OH.
Formulas for some alcohols and alkanes are listed below…
Methanol 
Butane 
Ethanol 
Ethane 
1-Propanol 
Propane 
Alcohols are sometimes used today as alternative fuels and as octane enhancers in fuel
for automobiles. Ethanol is combined with gasoline, for example, in a one-to-nine ratio
to produce gasohol. All simple alcohols are poisonous to some extent. When ethanol is
consumed, it is broken down by the enzyme alcohol dehydrogenase. Other simple alcohols
are attacked by alcohol dehydrogenase more slowly, making these alcohols more toxic then
ethanol. For example, methanol, or wood alcohol, is converted to formaldehyde and formic
acid, both of which are toxic. Toxic effects of methanol include damage to the optic
nerve, coma, and death.
Alkylhalides are organic compounds in which one or more halogen atoms-flourine, chlorine,
bromine, or iodine-are substituted for one or more hydrogen atoms in a hydrocarbon.
Because -X is often used to represent any halogen, an alkyl halide may be represented by
the general formula R-X. The formula for trichlorofluoromethane is:
The released chlorine atoms attack molecules of ozone (O3) found in the upper atmosphere.
The ozone is converted to diatomic oxygen. This makes it possible for a single chlorine
atom to destroy thousands of ozone molecules. Another alkyl halide is tetrafluoroethene.
It is joined in long chains to make a material with the trade name Teflon. Its formula is
C2F4.
Ethers are organic compounds in which two hydrocarbons groups are bonded to the same atom
of oxygen. They can be represented by the general formula R-O-R'. Methyl-tertiary-butyl
(MTBE) ether is the most widely used ether. It is another gasoline octane enhancer.
Aldehydes are organic compounds in which the carbonyl group is attached to a carbon atom
at the end of a carbon-atom chain. Ketones are organic compounds in which the carbonyl
group is attached to carbon atoms within the chain.
An example of one correctly named aldehyde and one correctly named ketone is:
The simplest aldehyde is methanal. It was once commonly used in biology laboratories as a
preservative for dead animals. Its most important commercial use, however, is in the
production of plastics. The simplest ketone is 2 propanone, whose common name is acetone.
Acetone is found in some nail-polish removers because it dissolves the organic substances
in nail polish. Aldehydes and ketones are also often responsible for odors and flavors.
Carboxylic acids are organic compounds that contain the carboxyl functional group. The
general formula is:
One correctly named carboxylic acid is:
A number of carboxylic acids occur naturally in plants and animal. For example, citrus
fruits contain citric acid. Carboxylic acids are also used as food additives to give a
tart or acidic flavor. Benzoic, propanoic, and sorbic acids are used as preservatives
that are able to kill microorganisms that cause food to spoil.
Esters are organic compounds with carboxylic acid groups in which the hydrogen of the
hydroxyl group has been replaced by an alkyl group. The general formula for an ester is:
Two examples of correctly named esters are:
Esters are common in plants and are responsible for some distinctive flavors and odors.
Isoamyl acetate, which is found in bananas, is also used as an artificial flavoring.
Amines are organic compounds that can be considered to be derivatives of ammonia. The
general formula is:
One correctly named amine is:
The formula for butrachotoxinin A, a toxic amine produced by a poison dart frog that
kills nerve cells, is:
Alkaloids are naturally occurring amine products of plans that have physiological effects
on animals. Examples of alkaloids include caffeine, nicotine, morphine, and coniine.
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